Metrology & Inspection Equipment

Film & Composition Metrology

Ellipsometry, XRF, XPS, and SIMS for film characterization

Film Thickness and Composition

Film Thickness and Composition

Key techniques for characterizing deposited films:

  • Spectroscopic Ellipsometry (SE): Measures how polarized light changes upon reflection from a film stack. Extracts thickness and optical constants for multiple layers simultaneously. The primary production tool for film thickness (1–10,000 nm range).
  • X-Ray Fluorescence (XRF): X-rays excite atoms in the film, which emit characteristic fluorescence. Provides composition and thickness for metal films. Non-destructive and fast.
  • X-Ray Photoelectron Spectroscopy (XPS): Measures the binding energies of photoelectrons to determine chemical composition and bonding states of surface layers. Critical for understanding gate stack chemistry.
  • SIMS (Secondary Ion Mass Spectrometry): Sputters the surface with an ion beam and analyzes ejected atoms with a mass spectrometer. Gives depth profiles of composition with ppb sensitivity. Destructive but uniquely powerful for dopant profiling.

AFM, TEM, and XRD — When You Need More Than a Spectrum

AFM, TEM, and XRD — When You Need More Than a Spectrum

Spectroscopic techniques give you film thickness and composition averaged over a spot. For the hardest characterisation questions — atom-scale geometry, lattice strain, true surface topography — three workhorse techniques take over:

TechniqueWhat it measuresResolutionThroughputTypical vendor
AFM (Atomic Force Microscopy)3D surface topography, roughness~0.1 nm Z, ~1 nm XYSlow (offline)Bruker, Park Systems
TEM (Transmission Electron Microscopy)Cross-section structure, atomic columns<0.1 nmDestructive, lab toolJEOL, Thermo Fisher (Titan)
XRD (X-Ray Diffraction)Lattice spacing, strain, crystallinity, textureLattice constants to ~10⁻⁴Inline-friendlyBruker, Rigaku, Jordan Valley
XRR (X-Ray Reflectivity)Film thickness (0.1–200 nm), density, roughness~Å thicknessInline-friendlyBruker, Rigaku

Where each is used in a modern fab flow

  • AFM — CMP step-height verification, line-edge roughness (LER) for FinFET fins, post-etch sidewall profile checks
  • TEM — failure analysis and process development. Focused-ion-beam (FIB) lift-out preps a ~50 nm cross-section that a TEM images at single-atom resolution. Indispensable for the first lots at a new node.
  • XRD — measure Ge fraction in SiGe (from peak shift) or strain in epitaxial layers; high-resolution XRD (HRXRD) is the inline tool for epi alloy composition
  • XRR — ultra-thin (1–5 nm) film thickness and density; complements ellipsometry where film optical properties are unknown

Key Concept: Why TEM Hasn't Gone Inline

TEM needs an electron-transparent sample, which means a destructive FIB lift-out. Sample prep alone takes hours per site. That's why TEM lives in failure-analysis labs while ellipsometry / OCD / XRR do the inline work on every wafer.

Knowledge Check

Knowledge Check

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Which technique provides non-destructive film thickness measurement for production monitoring?